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What are these harmonies?

This question is probably going to make me sound like a noob, but what type of harmonies is T-pain using in this song? There's just so many different harmonies going on. I can't pick them out and I don't have much experience with it. If that question doesn't make sense, then basically, how do I harmonize like t-pain in that song? What scales/chords/ whatever is he using?

Can anybody identify this sound?

I'm new here and I've been thinking about recording for fun when I have free time. I want to fill some songs out with the same sounds the Keith Urban has in the beggining of: "Somebody Like You" or "Raining on Sunday." Not sure if anybody has heard them, but I can't indentify the sound that both of the songs beggin with. Thanks, great website btw.